Structure and Properties of Crosslinked Polymers

Author: Gasan M Magomedov, Georgii V Kozlov and Gennady Zaikov
ISBN 978-1-84735-559-1

Published: 2011
Pages: 492, Hard cover

$205.00

Summary
Table of Contents

This book gives a fresh point of view on the curing processes, structure, and properties of crosslinked polymers. The general view is that the structure and properties of crosslinked polymers are defined by their density, this book demonstrates that the parameters are defined by the supermolecular (a more precisely, supersegmental structure) of the crosslinked polymers.

The quantitative relationships of the structures/properties are obtained for these polymers. Using an epoxy polymer as a nanofiller for a nanocomposite is discussed and a new class of polymer is proposed. The introduction of the nanofiller gives variation in the mechanical properties, the degree of crystallinity, gas permeability and so on. The use of these crosslinked polymers as natural nanocomposites is proposed. Practical methods of crosslinked polymer's supersegmental structure regulation are considered, and all the changes that this gives their properties are detailed.

This book will be of significance to all material scientists and students of material science.

1. The Main Principles of the Cluster Model
1.1 Fundamentals
1.2 Thermodynamics of the Local Order Formation
1.3 Polymer Structure Ordering Degree and Cluster Model
1.4 Thermofluctuational Origin of Clusters
1.5 Functionality of Clusters and Methods of its Estimation
2 The Main Physical Concepts used in Fractals Theory
2.1 The Fractal Analysis of Polymeric Media
2.2 The Fractal Models of Polymer Medium Structure
2.3 Polymer Medium with Scaling Theory Positions
2.4 The Fractal Analysis in Molecular Mobility Description Questions
3 The Fractal Models of Epoxy Polymers Curing Process
3.1 Two Types of Fractal Reactions at Curing of Crosslinked Epoxy Polymers
3.2 Scaling Relationships for Curing Reactions of Epoxy Polymers
3.3 Microgel Formation in the Curing Process of Epoxy Polymers
3.4 Synergetics of the Curing Process of Epoxy Polymers
3.5 The Nanodimensional Effects in the Curing Process of Epoxy Polymers into Fractal Space
4 The Description of Crosslinked Rubbers within the Frameworks of Fractal Analysis and Local Order Models
4.1 Molecular and Structural Characteristics of Crosslinked Polymer Networks
4.2 The Polychloroprene Crystallisation
4.3 The Cluster Model Application for the Description of the Process and Properties of Polychloroprene Crystallisation
4.4 Influence of Polychloroprene Crystalline Morphology on Its Mechanical Behaviour
5 Structure of Epoxy Polymers
5.1 Application of Wide Angle X-ray Diffraction for Study of the Structure of Epoxy Polymers
5.2 The Curing Influence on Molecular and Structural Characteristics of Epoxy Polymers
5.3 The Description of the Structure of Crosslinked Polymers within the Frameworks of Modern Physical Models
5.4 Synergetics of the Formation of Dissipative Structures in Epoxy Polymers
5.5 The Structural Analysis of Fluctuation Free Volume of Crosslinked Polymers
6 The Properties of Crosslinked Epoxy Polymers
6.1 The Glass Transition Temperature
6.2 Elasticity Moduli
6.3 Yield Stress
6.4 Fracture of Epoxy Polymers
6.5 The Other Properties
6.6 The Physical Ageing of Epoxy Polymers
7 Nanocomposites on the Basis of Crosslinked Polymers
7.1 The Formation of the Structure of Polymer/Organoclay Nanocomposites
7.2 The Reinforcement Mechanisms of Polymer/Organoclay Nanocomposites
7.3 The Simulation of Stress-strain Curves for Polymer/Organoclay Nanocomposites within the Frameworks of the Fractal Model
7.4 The Multifractal Model of Sorption Processes for Nanocomposites
8 Polymer-polymeric Nanocomposites
8.1 The Fractal Analysis of Crystallisation of Nanocomposites
8.2 The Melt Viscosity of HDPE/EP Nanocomposites
8.3 The Mechanical Properties of HDPE/EP Nanocomposites
8.4 The Diffusive Characteristics of HDPE/EP Nanocomposite
9 Crosslinked Epoxy Polymers as Natural Nanocomposites
9.1 Formation of the Structure of Natural Nanocomposites
9.2 The Properties of Natural Nanocomposites
10 The Solid-phase Extrusion of Rarely Crosslinked
Epoxy Polymers
Abbreviations
Index

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Mills, University of Birmingham, UK\u003cbr\u003e\u003cbr\u003e","published_at":"2017-06-22T21:15:06-04:00","created_at":"2017-06-22T21:15:06-04:00","vendor":"Chemtec Publishing","type":"Book","tags":["1995","additives","book","foam","impact properties","insulation","p-structural","polymer","polyurethane foams","recycling"],"price":6000,"price_min":6000,"price_max":6000,"available":true,"price_varies":false,"compare_at_price":null,"compare_at_price_min":0,"compare_at_price_max":0,"compare_at_price_varies":false,"variants":[{"id":43378463108,"title":"Default Title","option1":"Default Title","option2":null,"option3":null,"sku":"","requires_shipping":true,"taxable":true,"featured_image":null,"available":true,"name":"Cellular Polymers III","public_title":null,"options":["Default Title"],"price":6000,"weight":1000,"compare_at_price":null,"inventory_quantity":1,"inventory_management":null,"inventory_policy":"continue","barcode":"","requires_selling_plan":false,"selling_plan_allocations":[]}],"images":["\/\/chemtec.org\/cdn\/shop\/products\/978-1-85957-038-8.jpg?v=1499212420"],"featured_image":"\/\/chemtec.org\/cdn\/shop\/products\/978-1-85957-038-8.jpg?v=1499212420","options":["Title"],"media":[{"alt":null,"id":353968488541,"position":1,"preview_image":{"aspect_ratio":0.767,"height":450,"width":345,"src":"\/\/chemtec.org\/cdn\/shop\/products\/978-1-85957-038-8.jpg?v=1499212420"},"aspect_ratio":0.767,"height":450,"media_type":"image","src":"\/\/chemtec.org\/cdn\/shop\/products\/978-1-85957-038-8.jpg?v=1499212420","width":345}],"requires_selling_plan":false,"selling_plan_groups":[],"content":"\u003ch5\u003eDescription\u003c\/h5\u003e\nAuthor: Conference \u003cbr\u003eISBN 978-1-85957-038-8 \u003cbr\u003e\u003cbr\u003e25 papers, softbound\u003cbr\u003e\u003cbr\u003e\u003cbr\u003e\n\u003ch5\u003eSummary\u003c\/h5\u003e\n\u003cp\u003eThe material covers all aspects of elastomeric and rigid foams including: Thermal performance of insulating foams; Analysis of fire gases; The progress of CFC-free foams; Recycling and waste management; Gas transfer; Novel additives and synthesis techniques; Manufacturing developments for a range of foamed materials; Impact properties.\u003c\/p\u003e\n\u003cbr\u003e\n\u003ch5\u003eTable of Contents\u003c\/h5\u003e\nList of Papers: \u003cbr\u003e\u003cbr\u003eUse of the Distributed Parameter Continuum (DIPAC) Model for Estimating the Long Term Thermal Performance of Insulating Foams, Mark T. Bomberg and Mavinkal K Kumaran, National Research Council, Canada \u003cbr\u003e\u003cbr\u003eDevelopment of a Method tor Measuring Radial Creep of District Heating Pipes, H. D. Smidt, Danish Technological Institute, Denmark and L. Amby, Logstor Ror A\/S, Denmark \u003cbr\u003e\u003cbr\u003eUse of FTIR to Analyze Fire Gases from Burning Polyurethane Foams, K.T. Paul, Rapra Technology Limited, UK \u003cbr\u003e\u003cbr\u003eCFC-free Thermal Insulation Foams, C.W.F. Yu, D.R. Crump and D. Gardiner, Building Research Establishment, UK \u003cbr\u003e\u003cbr\u003eA Review of Life Cycle Assessment - A Tool for Measuring the Environmental Impact of Cellular Polymers, Dr David Heath, ICI Engineering Technology, UK and Dr. Vanja Markovic, ICI Polyurethanes\/ISOPA, Belgium \u003cbr\u003e\u003cbr\u003e\"CFC-Free\" The Scope of the Achievement so far, P. Ashford, Caleb Management Services, UK \u003cbr\u003e\u003cbr\u003eThe Future of Foam Plastic Insulation in the Light of Climate Chance Legislation, J.G. Abbott, Dow Europe SA., Switzerland \u003cbr\u003e\u003cbr\u003eProcess by which Controls on Chemicals are Introduced into European Community Legislation, J. Neill, European Commission, Belgium \u003cbr\u003e\u003cbr\u003eUtilization of Polymeric Isocyanate Based Binders in Recycling of Automotive Shredder Fluff, K.C. Frisch, A. Sendijarevic, V. Sendijarevic and D. Klempner, University of Detroit Mercy, USA \u003cbr\u003e\u003cbr\u003eRecovery and Recycling of Polyurethane Foams, E. Weigand, Bayer AG, Germany \u003cbr\u003e\u003cbr\u003eWaste Management of EPS in Europe, T. van Dorp, Shell Chemicals Europe, UK \u003cbr\u003e\u003cbr\u003eRecovery of Value from Waste: The Government View, P. Coombs, Department of Trade and Industry, UK \u003cbr\u003e\u003cbr\u003eCell Structure Development in Compression Molded, Crosslinked Polyethylene and Ethylene-Vinyl Acetate Foam, G.L.A. Sims and C. Khunniteekool, University of Manchester and UMIST, UK \u003cbr\u003e\u003cbr\u003eThe Influence of Low Molecular Additives on Gas Transport Properties in Polyethylene Films and Foams, W P Nauta and R.H.B. Bouma, University of Twente, J.E.F. Arnauts and H. M. Steuten, DSM Research, The Netherlands \u003cbr\u003e\u003cbr\u003ePolyether Triols,Tetrahydrofurame-Alkyleneoxides Copolymers for Flexible Polyurethane Foams, M. Ionescu, I. Mihalache, V. Zugravu and S. Mihai, Institute of Chemical Research, Romania \u003cbr\u003e\u003cbr\u003eSolubility and Nucleation Phenomena in Rigid PU Foam Expansion by Low Boiling Blowing Agents; a Modelling Approach, Henri J.M. Gruenbauer, Dow Benelux NV, The Netherlands \u003cbr\u003e\u003cbr\u003eLiquid Crystalline Polyurethanes: Synthesis, Properties and Application, B. Szczepaniak and P. Penczek, Industrial Chemistry Research Institute, A. Wolinska-Grabczyk, Institute of Coal Chemistry, and K.C. Frisch University of Detroit Mercy, USA \u003cbr\u003e\u003cbr\u003ePolyurethane Reactions According to Computational Chemistry, Nelson Malwitz, Sealed Air Corporation, USA \u003cbr\u003e\u003cbr\u003eRigid PVC Foams: A New Twist to an Old Technology, K. Redford, L.T. Hoydal, A. Stori, and K.H. Holm, SINTEF, Norway, A. Jorgensen and J. Grovdal, Dynoplast AS, Norway \u003cbr\u003e\u003cbr\u003eA Solid State Semi-Continuous Process to Make PET Foam Sheets, V. Kumar, University of Washington Seattle, USA and H. G. Schirmer, W. R. Grace Co., USA \u003cbr\u003e\u003cbr\u003eThe CarDio(TM) Process: Industrial Production Experiences, Carlo Florentini, Cannon Afros, Italy, Max Taverna, Cannon Communications, Italy, Barry Collings, Cannon, USA, Tony Griffiths, Cannon Viking, Italy \u003cbr\u003e\u003cbr\u003eThe Manufacture of Flexible Polyurethane Foams by the Variable Pressure Process V.P.F., J. B. Blackwell and G. Buckley, Beamech Group Limited, UK \u003cbr\u003e\u003cbr\u003eThe Balance of Formulation, Processing Conditions in the Manufacture of Crosslinked Polyethylene Foam, G.L.A. Sims and W. Sirithongtaworn, University of Manchester and UMIST, UK \u003cbr\u003e\u003cbr\u003eInteraction between Microstructure and Mechanical Properties of Flexible Polyurethane Foams, J. M. Williams and J. H. Beynon, University of Leicester, UK \u003cbr\u003e\u003cbr\u003eAnalysis of Impact of Two-Layer Foams, and Evaluation of Body Protectors, A. Gilchrist and N.J. Mills, University of Birmingham, UK\u003cbr\u003e\u003cbr\u003e"}