Handbook of Polyurethanes, Polyureas, and Polyisocyanurates

Handbook of Polyurethanes, Polyureas, and Polyisocyanurates

Author: George Wypych
ISBN 978-1-77467-092-7   

Published: May 2026
Pages: 530
Figures: 320
Tables: 80

$350.00

The Handbook of Polyurethanes, Polyureas, and Polyisocyanurates begins with an introduction defining key terms for understanding these versatile materials' chemistry and applications. Following this, a historical timeline provides context by tracing the development of polyurethanes from their inception to present-day innovations.

 

The handbook focuses heavily on the raw materials for polyurethane synthesis. It explores various isocyanates and polyols, detailing their chemical properties and roles in creating diverse polymer structures. The section also discusses amines, solvents, catalysts, and additives that enhance the synthesis process, including prepolymers, which serve as intermediates in production.

 

The text delves into typical methods of synthesis, examining the mechanisms of catalysis that speed up reactions, factors affecting reaction rates, and potential side reactions that can occur during polymerization. This leads to a discussion on the structures of linear and crosslinked polyurethanes, highlighting how these configurations influence the physical and chemical properties of the final products.

 

Understanding polyurethanes' domain morphology and crystalline structure is crucial, as these factors play a significant role in phase separation and hydrogen bonding, which impact material performance. The handbook also details typical methods for analyzing polyurethanes, allowing for assessment of their characteristics and qualities.

 

The following is a comprehensive review of the physical-mechanical properties of polyurethanes, addressing attributes such as elasticity, tensile strength, and thermal stability. The interactions between polyurethanes and various substrates are also explored, highlighting their compatibility in different applications.

 

Degradation mechanisms, including thermal, UV, and chemical degradation, and strategies for polyurethane stabilization to enhance durability are critically examined.

 

The handbook discusses the creation of polyurethane blends and interpenetrating networks, which can combine different material properties for improved performance.

An extensive section on additives used with polyurethanes covers a wide range of substances, such as plasticizers, pigments, flame retardants, and many others, each contributing to specific attributes in the final product.

The chapter on polyurethane processing outlines essential techniques, including metering, mixing, and storage, which are vital for efficient production.

 

In terms of applications, the handbook provides a thorough overview of the myriad uses of polyurethanes, from automotive parts and bedding to medical devices and packaging, emphasizing the properties and formulations unique to each application.

 

The handbook underscores the importance of health and safety by offering guidelines for safely handling and using polyurethane materials. Finally, it addresses waste disposal, processing, and recycling strategies, promoting environmentally responsible practices in the industry.

 

This summary encapsulates the core themes and topics of the handbook, providing an overview of what readers can expect from each section. The table of contents also includes concise information about the contents.

 

Here are some suggestions for potential users of the "Handbook of Polyurethanes, Polyureas, and Polyisocyanurates":

1. Researchers and Academics

·       Purpose: To gain comprehensive knowledge of polyurethane synthesis, properties, and applications.

·       Use: As a reference for literature reviews, experimental designs, and foundational understanding in materials science.

2. Chemists and Material Scientists

·       Purpose: To explore polyurethanes' chemical and physical properties and their raw materials.

·       Use: For guidance on material selection, synthesis techniques, and formulation development.

3. Industrial Engineers and Process Designers

·       Purpose: To understand the processing methods and operational parameters for manufacturing polyurethane products.

·       Use: As a resource for optimizing production processes and enhancing product quality.

4. Product Development Teams

·       Purpose: To develop new polyurethane-based products across various industries (e.g., automotive, construction, medical).

·       Use: For insights on additives, formulation strategies, and application-specific properties.

5. Quality Control and Assurance Professionals

·       Purpose: To ensure the quality and performance of polyurethane products.

·       Use: As a guide for analytical methods and testing protocols.

6. Environmental Scientists and Sustainability Experts

·       Purpose: To understand the environmental impact of polyurethane production and disposal.

·       Use: For strategies on waste management, recycling, and sustainable practices in the industry.

7. Health and Safety Officers

·       Purpose: To establish safety protocols and ensure compliance with regulations when handling polyurethanes.

·       Use: For guidelines on safe practices and material safety data.

8. Students and Educators

·       Purpose: To learn about polymer science and materials engineering.

·       Use: As a textbook or supplementary resource for coursework and research projects.

9. Consultants and Industry Experts

·       Purpose: To provide informed advice to companies on polyurethane applications and innovations.

·       Use: As a comprehensive source for current knowledge and trends in polyurethane technology.

10. Manufacturers of Polyurethane Products

·       Purpose: To stay updated on the latest developments and best practices in polyurethane technology.

·       Use: For insights into formulation, processing, and application methods.

 

1.    Introduction  – definition of terms
2.    Historical timeline
3.    Raw materials for polyurethane synthesis
a.    Isocyanates
b.    Polyols
c.    Amines
d.    Non-isocyanate synthesis components (cyclic carbonates and amines)
e.    Solvents
f.    Catalysts
g.    Blocking agents
h.    Other additives
4.    Typical methods of synthesis
a.    Mechanisms of catalysis
b.    Reaction rates
c.    Side reactions (allophanates, biurets, carbodiimides, and dimers)
5.    Structures of linear and crosslinked polyurethanes 
6.    Domain morphology
7.    Crystalline structure, phase separation, and hydrogen bonding
8.    Typical methods of polyurethane analysis
9.    Physical-mechanical properties of polyurethanes
10.    Interaction with other materials (substrates
11.    Polyurethane degradation
a.    Thermal
b.    UV
c.    Chemical
12.    Polyurethane stabilization
13.    Polyurethane blends and interpenetrating networks
14.    Additives used with polyurethanes 
a.    Plasticizers 
b.    Pigments 
c.    Blowing agents
d.    Surfactants 
e.    Adhesion promoters
f.    Rheological additives
g.    Fillers and nanofillers 
h.    Flame retardants
i.    Antibacterial additives
15.    Polyurethane processing
a.    Prepolymers processing
b.    Storage 
c.    Metering
d.    Mixing 
16.    Applications, properties, and formulations
a.    3D printing
b.    Adhesives and sealants
c.    Appliances
d.    Artificial leather
e.    Automotive
f.    Bedding 
g.    Building and construction
h.    Carpet underlay
i.    Coatings and paints
j.    Composite wood
k.    Electrical and electronics
l.    Fiber and textiles
m.    Flooring
n.    Foams 
o.    Footwear 
p.    Furniture
q.    Marine
r.    Roofing
s.    Medical
t.    Packaging
u.    Pharmaceutical 
v.    Reaction injection molding
w.    Seals and gaskets
x.    Shape memory
y.    Sporting equipment
z.    Straps 
aa.    Tires
bb.    Waterproofing
17.    Health and safety
18.    Waste disposal, processing, and recycling

 

George Wypych has PhD Eng. The professional expertise includes university teaching (full professor) and research & development (university and corporate). He has published 48 books (PVC Plastisols, Wroclaw University Press; Polyvinylchloride Degradation, Elsevier; Polyvinylchloride Stabilization, Elsevier; Polymer Modified Textile Materials, Wiley & Sons; Handbook of Material Weathering, 1st, 2nd, 3rd, 4th, 5th, 6th Edition, ChemTec Publishing; Handbook of Fillers, 1st, 2nd, 3rd, 4th, and 5th Edition, ChemTec Publishing; Recycling of PVC, ChemTec Publishing; Weathering of Plastics. Testing to Mirror Real Life Performance, Plastics Design Library, Handbook of Solvents, Vol. 1. Properties 1st, 2nd, and 3rd Edition, ChemTec Publishing, Handbook of Solvents, Vol. 2. Health & Environment 1st, 2nd, and 3rd Edition, ChemTec Publishing, Handbook of Plasticizers, 1st, 2nd, 3rd, 4th Edition, ChemTec Publishing, Handbook of Antistatics, 1st and 2nd Edition, ChemTec Publishing, Databook of Antistatics, 1st and 2nd Edition, ChemTec Publishing, Handbook of Antiblocking, Release and Slip Additives, 1st , 2nd and 3rd Edition, ChemTec Publishing, Industrial Solvents in Kirk-Othmer Encyclopedia of Chemical Technology (two editions), John Wiley & Sons, PVC Degradation & Stabilization, 1st, 2nd, 3rd, and 4th Editions, ChemTec Publishing, The PVC Formulary, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Material Biodegradation, Biodeterioration, and Biostabilization, 1st and 2nd Editions, ChemTec Publishing, Handbook of UV Degradation and Stabilization, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Polymers, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Atlas of Material Damage, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Odors in Plastic Materials, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Databook of Solvents (two editions), ChemTec Publishing, Databook of Blowing and Auxiliary Agents, ChemTec Publishing, Handbook of Foaming and Blowing Agents (two editions), ChemTec Publishing, Databook of Green Solvents, ChemTec Publishing (two editions), Self-healing Products (two editions), ChemTec Publishing, Handbook of Adhesion Promoters (two editions), ChemTec Publishing, Databook of Surface Modification Additives (two editions), ChemTec Publishing, Handbook of Surface Improvement and Modification (two editions), ChemTec Publishing, Graphene – Important Results and Applications, ChemTec Publishing, Handbook of Curatives and Crosslinkers, ChemTec Publishing, Chain Mobility and Progress in Medicine, Pharmaceutical, Polymer Science and Technology, Impact of Award, ChemTec Publishing, Databook of Antioxidants, ChemTec Publishing, Handbook of Antioxidants, ChemTec Publishing, Databook of UV Stabilizers (two Editions), ChemTec Publishing, Databook of Flame Retardants, ChemTec Publishing, Databook of Nucleating Agents, ChemTec Publishing, Handbook of Flame Retardants, ChemTec Publishing, Handbook of Nucleating Agents, ChemTec Publishing, Handbook of Polymers in Electronics, ChemTec Publishing, Databook of Impact Modifiers, ChemTec Publishing, Databook of Rheological Additives, ChemTec Publishing, Handbook of Impact Modifiers, ChemTec Publishing, Handbook of Rheological Additives, ChemTec Publishing, Databook of Polymer Processing Additives, ChemTec Publishing, Handbook of Polymer Processing Additives, ChemTec Publishing, Functional Fillers (two editions), 2 databases (Solvents Database, 1st, 2nd, 3rd Edition and Database of Antistatics 1st and 2nd Edition, both by ChemTec Publishing), and 42 scientific papers and obtained 16 patents. He specializes in PVC, polymer additives, material durability, and the development of sealants and coatings. He was included in the Dictionary of International Biography, Who's Who in Plastics and Polymers, and Who's Who in Engineering, and was selected International Man of the Year 1996-1997 in recognition of services to education.